Talking from my own personal experience being in this exact situation a while back, the 780ti on it's own may give similar numbers on paper, but in real terms it blows the 2 580's out of the water. I ran 2 Asus DCU2 580's in SLI and then switched to a 780ti.
First, as goliath said, they are 1.5gb, and even when in SLI will still only be 1.5gb. Not each, remember they don't combine, so a total of 1.5gb. Modern 3d applications blow through that pretty quick, and it's only going to get worse. I've already hit the 3gb cap on the 780ti's once or twice. Second, they were made using older architecture, meaning no newer features such as shadowplay are available. Personally I found that they struggled a bit in newer games, especially those that take full advantage of dx11. To get them up to par I had to give them a bit of overclock, which naturally sent the heat and noise up. Third, depending on the brand, I would definitely recommend more than a 650w PSU. The DCU's peaked at around 290w without OC, so for SLI and possibly some OC room I wouldn't go less than 800w.
All in all, upgrading from the 580's to a 780ti was worth every cent to me. The 580 is still a great card, but it makes more sense in the long run to go for a newer 700 or 900 series card imho.